Wouthuysen–Field coupling
Open-knowledge reference entry
Wouthuysen–Field coupling, or the Wouthuysen–Field effect, is a mechanism that couples the excitation temperature, also called the spin temperature, of neutral hydrogen to Lyman-alpha radiation. This coupling plays a role in producing a difference in the temperature of neutral hydrogen and the cosmic microwave background at the end of the Dark Ages and the beginning of the epoch of reionization. It is named for Siegfried Adolf Wouthuysen and George B. Field.
Background
The period after recombination occurred and before stars and galaxies formed is known as the "dark ages". During this time, the majority of matter in the universe is neutral hydrogen. This hydrogen has yet to be observed, but there are experiments underway to detect the hydrogen line produced during this era. The hydrogen line is produced when an electron in a neutral hydrogen atom is excited to the triplet spin state, or de-excited as the electron and proton spins go to the singlet state. The energy difference between these two hyperfine states is
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{\displaystyle 5.9\times 10^{-6}}
electron volts, with a wavelength of 21 centimeters. At times when neutral hydrogen is in thermodynamic equilibrium with the photons in the cosmic microwave background (CMB), the neutral hydrogen and CMB are said to be "coupled", and the hydrogen line is not observable. It is only when the two temperatures differ, i.e.
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