Superstatistics

Superstatistics is a branch of statistical mechanics or statistical physics devoted to the study of non-linear and non-equilibrium systems. It is characterized by using the superposition of multiple differing statistical models to achieve the desired non-linearity. In terms of ordinary statistical ideas, this is equivalent to compounding the distributions of random variables and it may be considered a simple case of a doubly stochastic model.

Consider an extended thermodynamical system which is locally in equilibrium and has a Boltzmann distribution, that is the probability of finding the system in a state with energy

E

{\displaystyle E}

is proportional to

exp

⁡

(

−

β

E

)

{\displaystyle \exp(-\beta E)}

. Here

β

{\displaystyle \beta }

is the local inverse temperature. A non-equilibrium thermodynamical system is modeled by considering macroscopic fluctuations of the local inverse temperature. These fluctuations happen on time scales which are much larger than the microscopic relaxation times to the Boltzmann distribution. If the fluctuations of

β

{\displaystyle \beta }

are characterized by a distribution

f

(

β

)

{\displaystyle f(\beta )}

, the superstatistical Boltzmann factor of the system is given by

B

(

E

)

=

∫

0

∞

d

β

f

(

β

)

exp

⁡

(

−

β

E

)

.

{\displaystyle B(E)=\int _{0}^{\infty }d\beta f(\beta )\exp(-\beta E).}

This defines the superstatistical partition function

Z

=

∑

i

=

1

W

B

(

E

i

)

{\displaystyle Z=\sum _{i=1}^{W}B(E_{i})}

for system that can assume discrete energy states

{

E

i

}

i

=

1

W

{\displaystyle \{E_{i}\}_{i=1}^{W}}

. The probability of finding the system in state

E

i

{\displaystyle E_{i}}

is then given by

p

i

=

1

Z

B

(

E

i

)

.