Reactive dye
type of dyes

In a reactive dye, a chromophore (an atom or group whose presence is responsible for the colour of a compound) contains a substituent that reacts with the substrate. Reactive dyes have good fastness properties owing to the covalent bonding that occurs during dyeing. Reactive dyeing is the most important method for coloring cellulose fibers. Reactive dyes can also be applied on wool and nylon; in the latter case they are applied under weakly acidic conditions. Reactive dyes have a low utilization degree compared to other types of dyestuff, since the functional group also bonds to water, creating hydrolysis.
Usage
Reactive dyes had been tested in the late 1800s involving both adding functionalized dyes to the substrate and then activating the substrate first followed by fixation of the dye. The first commercial success was described in the early 1950s. Rattee and Stephens at Imperial Chemical Industries (ICI) popularized the chlorotriazines as linkers between the substrate and the chromophore.
Trichlorotriazine remain a popular platform for reactive dyes. The chromophore, with an amine functional group, is attached to the triazine, displacing one chloride:
(NCCl)3 + dye-NH2 → N3C3Cl2(NHdye) + HCl
The resulting dichlorotriazine can then be affixed to the cellulose fibre by displacement of one of the two chloride groups:
N3C3Cl2(NHdye) + HO-cellulose → N3C3Cl(NHdye)(O-cellulose) + HCl
The fixation process is conducted in a buffered alkaline dye bath.
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