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Reactive dye

type of dyes

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Record originEnglish Wikipedia
Text licenseCC BY-SA 4.0
Source revisionNov 11, 2024
Entity authorityQ1132457
Source-derived summary

In a reactive dye, a chromophore (an atom or group whose presence is responsible for the colour of a compound) contains a substituent that reacts with the substrate. Reactive dyes have good fastness properties owing to the covalent bonding that occurs during dyeing. Reactive dyeing is the most important method for coloring cellulose fibers. Reactive dyes can also be applied on wool and nylon; in the latter case they are applied under weakly acidic conditions. Reactive dyes have a low utilization degree compared to other types of dyestuff, since the functional group also bonds to water, creating hydrolysis.

Usage

Reactive dyes had been tested in the late 1800s involving both adding functionalized dyes to the substrate and then activating the substrate first followed by fixation of the dye. The first commercial success was described in the early 1950s. Rattee and Stephens at Imperial Chemical Industries (ICI) popularized the chlorotriazines as linkers between the substrate and the chromophore.

Trichlorotriazine remain a popular platform for reactive dyes. The chromophore, with an amine functional group, is attached to the triazine, displacing one chloride:

(NCCl)3 + dye-NH2 → N3C3Cl2(NHdye) + HCl

The resulting dichlorotriazine can then be affixed to the cellulose fibre by displacement of one of the two chloride groups:

N3C3Cl2(NHdye) + HO-cellulose → N3C3Cl(NHdye)(O-cellulose) + HCl

The fixation process is conducted in a buffered alkaline dye bath.

Editorial summary

This brief starts where responsible research should: with the source description of “Reactive dye” as type of dyes. Everything that follows is an evidence route, not borrowed authority.

Editorial reviewA dependable orientation record for establishing vocabulary, names and a first evidence trail. The current 225-word lead offers orientation but no explicit four-digit date, so chronology should not be assumed. The selected authority fields contribute no independent date. The account is most persuasive where Reactive, type and dyes can be independently traced.
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The subject matters to the general reference register because the source frames it as type of dyes. Its deeper value depends on whether names, dates, institutions and citations support that framing.

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Vocabulary and entity names are the principal evidence signals here, because they determine the precision of every later search. The source revision retrieved here is dated Nov 11, 2024. The linked authority identifier is Q1132457. None of the 0 selected statements returned an explicit reference.

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This entry incorporates text from Reactive dye” on English Wikipedia. Contributors are listed in the page history. Text is available under the Creative Commons Attribution-ShareAlike 4.0 License. Selected authority identifiers and statements are retrieved from Wikidata under CC0; their references and qualifiers remain part of the verification path.