Isotopes of krypton
isotopes of the element Krypton

There are 34 known isotopes of krypton (36Kr) with atomic mass numbers from 67 to 103. Naturally occurring krypton is made of five stable isotopes and one (78Kr) which is slightly radioactive with an extremely long half-life, plus traces of radioisotopes that are produced by cosmic rays in the atmosphere. Atmospheric krypton today is, however, considerably radioactive due almost entirely to artificial 85Kr.
List of isotopes
Notable isotopes
Krypton-81
Krypton-81 (half-life 230,000 years) is useful in determining how old the water beneath the ground is. Radioactive krypton-81 is the product of spallation reactions with cosmic rays striking gases present in the Earth atmosphere, along with the six stable or nearly stable krypton isotopes. The long half-life ensures that the isotope has a uniform concentration in the atmosphere and in surface water; when the water goes underground is supply is no longer replenished and decays, allowing dating of the residence time in deep aquifers in a range of 20,000 to a million years, bridging the gap where other isotopic methods (e.g. carbon-14 dating) lose sensitivity. The same long half-life renders detection of its decay impossible and, therefore, demands some form of mass spectrometry. Even so, technical limitations of the method have traditionally required the sampling of very large volumes of water: several hundred liters or a few cubic meters of water (about a milligram of krypton). This is particularly challenging for dating pore water in deep clay aquitards with very low hydraulic conductivity.
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