Gibbsite
form of aluminium hydroxide, mineral
Gibbsite, Al(OH)3, is one of the mineral forms of aluminium hydroxide. It is often designated as γ-Al(OH)3 (but sometimes as α-Al(OH)3). It is also sometimes called hydrargillite (or hydrargyllite).
Gibbsite is an important ore of aluminium in that it is one of three main phases that make up the rock bauxite.
Gibbsite has three named structural polymorphs or polytypes: bayerite (designated often as α-Al(OH)3, but sometimes as β-Al(OH)3), doyleite, and nordstrandite. Gibbsite can be monoclinic or triclinic, while bayerite is monoclinic. Doyleite and nordstrandite are triclinic forms.
Structure
The structure of gibbsite is interesting and analogous to the basic structure of the micas. The basic structure forms stacked sheets of linked octahedra. Each octahedron is composed of an aluminium ion bonded to six hydroxide groups, and each hydroxide group is shared by two aluminium octahedra.
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