Hartree–Fock method

In computational physics and chemistry, the Hartree–Fock (HF) method is used for approximating the wave function and the energy of a quantum many-body system in a stationary state. It is named after Douglas Hartree and Vladimir Fock.

The Hartree–Fock method often assumes that the exact

N

{\displaystyle N}

-body wave function of the system can be approximated by a single Slater determinant (in the case where the particles are fermions) or by a single permanent (in the case of bosons) of

N

{\displaystyle N}

spin-orbitals. By invoking the variational method, one can derive a set of

N

{\displaystyle N}

coupled equations for the

N

{\displaystyle N}

spin orbitals. A solution of these equations yields the Hartree–Fock wave function and energy of the system. Hartree–Fock approximation is an instance of mean-field theory, where neglecting higher-order fluctuations in order parameter allows interaction terms to be replaced with quadratic terms, obtaining exactly solvable Hamiltonians.

Especially in the older literature, the Hartree–Fock method is also called the self-consistent field method (SCF). In deriving what is now called the Hartree equation as an approximate solution of the Schrödinger equation, Hartree required the final field as computed from the charge distribution to be "self-consistent" with the assumed initial field. Thus, self-consistency was a requirement of the solution. The solutions to the non-linear Hartree–Fock equations also behave as if each particle is subjected to the mean field created by all other particles (see the Fock operator below), and hence the terminology continued.