Electro-galvanic oxygen sensor
device which produces a voltage by a chemical reaction with oxygen proportional to partial pressure
An electro-galvanic fuel cell is an electrochemical device which consumes a fuel to produce an electrical output by a chemical reaction. One form of electro-galvanic fuel cell based on the oxidation of lead is commonly used to measure the concentration of oxygen gas in underwater diving and medical breathing gases.
Electronically monitored or controlled diving rebreather systems, saturation diving systems, and many medical life-support systems use galvanic oxygen sensors in their control circuits to directly monitor oxygen partial pressure during operation. They are also used in oxygen analysers in recreational, technical diving and surface supplied mixed gas diving to analyse the proportion of oxygen in a nitrox, heliox or trimix breathing gas before a dive.
These cells are lead/oxygen galvanic cells where oxygen molecules are dissociated and reduced to hydroxyl ions at the cathode. The ions diffuse through the electrolyte and oxidize the lead anode. A current proportional to the rate of oxygen consumption is generated when the cathode and anode are electrically connected through a resistor
Function
The cell reaction for a lead/oxygen cell is: 2Pb + O2 → 2PbO, made up of the cathode reaction: O2 + 2H2O + 4e− → 4OH−, and anode reaction: 2Pb + 4OH− → 2PbO + 2H2O + 4e−.
The cell current is proportional to the rate of oxygen reduction at the cathode, but this is not linearly dependent on the partial pressure of oxygen in the gas to which the cell is exposed: Linearity is achieved by placing a diffusion barrier between the gas and the cathode, which limits the amount of gas reaching the cathode to an amount that can be fully reduced without significant delay, making the partial pressure in the immediate vicinity of the electrode close to zero. As a result of this the amount of oxygen reaching the electrode follows Fick's laws of diffusion and is proportional to the partial pressure in the gas beyond the membrane. This makes the current proportional to PO2.
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