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COLEX process

method of isotopic separation of lithium-6 and lithium-7

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Record originEnglish Wikipedia
Text licenseCC BY-SA 4.0
Source revisionMar 2, 2026
Entity authorityQ39905370
Source-derived summary

The COLEX process (or COLEX separation) is a chemical method of isotopic separation of lithium-6 and lithium-7, based on the use of mercury. COLEX stands for column exchange.

Since the beginning of the atomic era, a variety of lithium enrichments methods have been developed (such as chemical exchange, electromagnetic, laser, centrifugal) and the COLEX process has been the most extensively implemented method so far.

Early development

In the US, several chemical exchange methods for lithium isotope separation have been under investigation in the 1930s and 1940s to develop a process for lithium-6 production, so that tritium could be obtained for thermonuclear weapons research.

The system finally selected was the COLEX process, with aqueous lithium hydroxide (LiOH) contacted with lithium-mercury amalgam. This process was initially used in the US between 1955 and 1963 in the Y12 plant in Oak Ridge, Tennessee. The COLEX plants in Oak Ridge had a very rough start in 1955 with major problems in this entirely new, complicated, and potentially hazardous technology. Stockpiles of lithium-6 and lithium-7 from that period have been available until recently to meet the relatively small domestic and world demand

Since then, due to environmental concerns, the US has stopped lithium enrichments operations in 1963.

South Africa also built a pilot plant using the COLEX method to make lithium-6 for its nuclear weapons program in the 1970s.

Lithium isotopes and uses

Natural lithium contains about 7.5% lithium-6 ( 63Li ), with the rest being lithium-7 ( 73Li ).

Editorial summary

Begin with the source’s own compact description: “COLEX process” is method of isotopic separation of lithium-6 and lithium-7. The dossier treats that line as a proposition to test through COLEX, process and method, not as a finished interpretation.

Editorial reviewA dependable orientation record for establishing vocabulary, names and a first evidence trail. The current lead gives the account dated anchors—1955, 1963—that can be checked directly. The selected authority fields contribute no independent date. For this dossier, COLEX, process and method is the immediate research focus.
Editorial analysis

Why this record matters

The phrase “method of isotopic separation of lithium-6 and lithium-7” supplies a clear boundary for inquiry. It also exposes the unanswered questions: who defined that boundary, when it became stable and which sources sit outside it.

Evidence profile

Vocabulary and entity names are the principal evidence signals here, because they determine the precision of every later search. The source revision retrieved here is dated Mar 2, 2026. The linked authority identifier is Q39905370. None of the 0 selected statements returned an explicit reference. The first chronological checks are 1955 and 1963.

Critical limits

A concise general-reference account can conceal disagreements about scope, terminology or the weight assigned to individual sources. The lead is largely declarative, so disagreement and counter-evidence require a deliberate search beyond the opening account. Authority statements aid reconciliation but still require their own references, qualifiers and ranks to be checked.

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Use the entry as an orientation point, then follow its citations and revision history. Names, dates and institutional relationships should be checked against the original record.

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Source & attribution

This entry incorporates text from COLEX process” on English Wikipedia. Contributors are listed in the page history. Text is available under the Creative Commons Attribution-ShareAlike 4.0 License. Selected authority identifiers and statements are retrieved from Wikidata under CC0; their references and qualifiers remain part of the verification path.