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Bicapped trigonal prismatic molecular geometry

Shape in molecular geometry

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Record originEnglish Wikipedia
Text licenseCC BY-SA 4.0
Source revisionFeb 14, 2024
Entity authorityQ60785407 ↗
Source-derived summary

In chemistry, the bicapped trigonal prismatic molecular geometry describes the shape of compounds where eight atoms or groups of atoms or ligands are arranged around a central atom defining the vertices of a biaugmented triangular prism. This shape has C2v symmetry and is one of the three common shapes for octacoordinate transition metal complexes, along with the square antiprism and the dodecahedron.

It is very similar to the square antiprismatic molecular geometry, and there is some dispute over the specific geometry exhibited by certain molecules. One example of the bicapped trigonal prismatic molecular geometry is the ZrF4−8 ion.

The bicapped trigonal prismatic coordination geometry is found in the plutonium(III) bromide crystal structure type, which is adopted by many of the bromides and iodides of the lanthanides and actinides.

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“Bicapped trigonal prismatic molecular geometry” enters the record as shape in molecular geometry. Crown Archives preserves that source wording while asking what Bicapped, trigonal and prismatic can confirm, complicate or overturn.

Editorial reviewA dependable orientation record for establishing vocabulary, names and a first evidence trail. The current 128-word lead offers orientation but no explicit four-digit date, so chronology should not be assumed. The selected authority fields contribute no independent date. Its strongest next move is a source search built around Bicapped, trigonal and prismatic.
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This entry incorporates text from “Bicapped trigonal prismatic molecular geometry” on English Wikipedia. Contributors are listed in the page history. Text is available under the Creative Commons Attribution-ShareAlike 4.0 License. Selected authority identifiers and statements are retrieved from Wikidata under CC0; their references and qualifiers remain part of the verification path.